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EACON 2020

EurAsian Conference on Nanophotonics

April 6 – 9, 2020 / Jena, Germany

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Tiow-Gan Ong

Institute of Chemistry, Academia Sinica, 12345 Taipei, TAIWAN
Department of Chemistry, National Taiwan University, 10611 Taipei, TAIWAN

Carbodicarbene, Carbogenic Maverick, Not a Moderate!

Carbone is a special class of carbon compound with a structural CL2 that feature a dicoordinated central carbon (0) bearing two lone pairs of electrons flanked by dative ligands (L) units. When L is an NHC or carbene, a particular carbone with a carbon→carbon dative bond is formed. This carbone species is classified as a carbodicarbene (CDC) with a formulation of NHCCNHC. Due to the two lone pairs on the central carbon, carbone or carbodicarbene has a strong σ-donating scaffold. In describe the development of a synthetic protocol for the preparation of carbodicarbenes with unsymmetrical side arms and investigate their late transition metal complexes and intrinsic reactivities. The ligand carbodicarbene is used for possible catalysis application and main group chemistry.

References

  1. Hsu, Y.-C.; Wang, V. C.-C.; Au-Yeung, K.-C.; Tsai, C.-Y.; Chang, C.-C.; Lin, B.-C.; Chan, Y.-T.; Hsu, C.-P.; Yap, G. P. A.; Jurca,* T.; Ong, T.-G.* One-Pot Tandem Photoredox and Cross-Coupling Catalysis with a Single Pd-Carbodicarbene Complex. Angew. Chem. Int. Ed. 2018, 57, 4622-4626.
  2. W.-C. Chen, W.-C. Shih, T. Jurca, L. Zhao, D. M. Andrada, C.-J. Peng, C.-C. Chang, S.-k. Liu, Y.-P. Wang, Y.-S. Wen, G. P. A. Yap, C.-P. Hsu, G. Frenking, T.-G. Ong. J. Am. Chem. Soc. 2017, 139, 12830-12836.
  3. Chen, W.-C.; Shen, J.-S.; Jurca, T.; Peng, C.-J.; Lin, Y. H.; Wang, Y.-P.; Shih, W.-C.; Yap, G. P. A.; Ong, T.-G.* Angew. Chem. Int. Ed., 2015, 54, 15307-15212.
  4. Hsu, Y.-C.; Shen, J.-S.; Lin, B.-C.; Chen, W.-C.; Chan, Y.-T.; Ching, W.-M.; Yap, G. P. A.; Hsu, C.-P.; Ong, T.-G.* Angew. Chem. Int. Ed., 2015, 54, 2420-2424.
  5. Chen, C.-C.; Lee, C.-Y.; Lin, B.-C.; Hsu, Y.-C.; Shen, J.-S.; Hsu, C.-P.; Yap, G. P. A.; Ong, T.-G.* J. Am. Chem. Soc., 2014, 136, 914-917.

Further Talks

Andrea Csáki

Microfludic Synthesis of plasmonic Nanoparticles for Sensing Applications

Andrey Turchanin

Controlled growth of transition metal dichalcogenide monolayers for applications in nanoelectronic and nanophotonic devices

Chi Chen

Near Field Spectroscopic Imaging: from Hard to Soft Materials

Chi-How Peng

Cobalt mediated controlled/living radical polymerization: from mechanism understanding to materials application

Chun-Hong Kuo

Bridging Energy and Chemistry via Nanoarchitectonic Engineering at Atomic Scale

Falk Eilenberger

Integration of two-dimensional materials in optical systems for nonlinear optics, sensing, and single photon sources

Frank Setzpfandt

Nonlinear frequency conversion in nanostructured optical systems for application in quantum photonics

Heng-Liang Wu

Controlling the Oxidation State of Cu Electrode and Reaction Intermediates for Electrochemical CO2 Reduction to Ethylene

Kien-Voon Kong

Direct Observation of Reaction Intermediates of Metal-based Therapeutic Agents in Single Living Cell Using TERS

Maria Wächtler

Quantum confined semiconductor nanostructures in light-driven catalysis

Martin Presselt

Supramolecular Control of Optical and Electronical Properties of Two-Dimensional Dye Layers

Po-Chiao Lin

New Environment Sensitive Fluorophores with Color-Tailored Emission: In Vivo Monitoring of Carbonic Anhydrases Expression on Growth of Larval Zebrafish

Shangjr (Felix) Gwo

Plasmonic Metasurface-Enhanced Linear and Nonlinear Processes in Two-Dimensional Semiconductors

Ta-Jen Yen

Empowering Bilayer MoS2 by Engineered Plasmonic Nanostructures for Optoelectronic Applications

Tiow-Gan Ong

Carbodicarbene, Carbogenic Maverick, Not a Moderate!

Volker Deckert

Plasmon Enhanced Probe Spectroscopies – Structural Investigation of Nanoscale Objects

Yi-Tsu Chan

Molecular self-assembly methodology for rational construction of metallosupramolecules with high structural complexity

Yian Tai

Toward a universal polymeric material for electrode buffer layers in organic optoelectronics

Yu-Jung Lu

Controlling Light-matter Interactions at Nanoscale with Plasmonics: From Spontaneous Emission to Lasing